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Thermodynamics and Micro Heterogeneity of Ionic Liquids

Kirchner, Barbara

Ionic Liquids, 2009, Vol.290, p.161-183 [Periódico revisado por pares]

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Título:
Thermodynamics and Micro Heterogeneity of Ionic Liquids
Autor: Kirchner, Barbara
Assuntos: Force-field ; Inorganic Chemicals ; Ionic liquids ; Ionic Liquids - chemistry ; Molecular simulation ; Nanosegregation ; Solubility ; Solvents - chemistry ; Temperature ; Thermodynamics
É parte de: Ionic Liquids, 2009, Vol.290, p.161-183
Notas: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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Descrição: The high degree of organisation in the fluid phase of room-temperature ionic liquids has major consequences on their macroscopic properties, namely on their behaviour as solvents. This nanoscale self-organisation is the result of an interplay between two types of interaction in the liquid phase – Coulomb and van der Waals – that eventually leads to the formation of medium-range structures and the recognition of some ionic liquids as composed of a high-charge density, cohesive network permeated by low-charge density regions. In this chapter, the structure of the ionic liquids will be explored and some of their consequences to the properties of ionic liquids analyzed.
Títulos relacionados: Topics in Current Chemistry
Editor: Germany: Springer Berlin / Heidelberg
Idioma: Inglês

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