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Chemical environment and Ce valence: global trends in transition-metal compounds

NEIFELD, R. A ; CROFT, M ; MIHALISIN, T ; SEGRE, C. U ; MADIGAN, M ; TORIKACHVILI, M. S ; MAPLE, M. B ; DELONG, L. E

Phys. Rev. B: Condens. Matter; (United States), 1985-11, Vol.32 (10), p.6928-6931

Woodbury, NY: American Physical Society

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Título:
Chemical environment and Ce valence: global trends in transition-metal compounds
Autor: NEIFELD, R. A ; CROFT, M ; MIHALISIN, T ; SEGRE, C. U ; MADIGAN, M ; TORIKACHVILI, M. S ; MAPLE, M. B ; DELONG, L. E
Assuntos: 360603 - Materials- Properties ; 400201 - Chemical & Physicochemical Properties ; ABSORPTION SPECTRA ; CERIUM COMPOUNDS ; CHEMICAL PROPERTIES ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Cross-disciplinary physics: materials science; rheology ; DATA ; ELECTRONIC STRUCTURE ; ENVIRONMENT ; Exact sciences and technology ; EXPERIMENTAL DATA ; HYBRIDIZATION ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; MAGNETIC PROPERTIES ; MAGNETIC SUSCEPTIBILITY ; MATERIALS SCIENCE ; Metals, semimetals and alloys ; NUMERICAL DATA ; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation ; Other interactions of matter with particles and radiation ; PHYSICAL PROPERTIES ; Physics ; RARE EARTH COMPOUNDS ; Specific materials ; SPECTRA ; TRANSITION ELEMENT COMPOUNDS ; VALENCE
É parte de: Phys. Rev. B: Condens. Matter; (United States), 1985-11, Vol.32 (10), p.6928-6931
Notas: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
AS05-82ER12061; AS03-76ER70227
Descrição: Results of L/sub III/ absorption spectroscopy measurements on a wide range of Ce--transition-metal (T) compounds are presented and Ce valence-state estimates are made. We are able to identify extremely regular trends in the response of the Ce valence and Ce-T hybridization strength to systematic variations in the solid-state chemical environment. Our work facilitates identification of the specific elements in the T-metal electronic structure which drive the Ce valence-state change.
Editor: Woodbury, NY: American Physical Society
Idioma: Inglês

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Chemical environment and Ce valence: global trends in transition-metal compounds

NEIFELD, R. A ; CROFT, M ; MIHALISIN, T ; SEGRE, C. U ; MADIGAN, M ; TORIKACHVILI, M. S ; MAPLE, M. B ; DELONG, L. E

Woodbury, NY: American Physical Society

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