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HCSiF and HCSiCl: The First Detection of Molecules with Formal C≡Si Triple Bonds

Karni, Miriam ; Apeloig, Yitzhak ; Schröder, Detlef ; Zummack, Waltraud ; Rabezzana, Roberto ; Schwarz, Helmut

Angewandte Chemie (International ed.), 1999-02, Vol.38 (3), p.331-335 [Periódico revisado por pares]

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Título:
HCSiF and HCSiCl: The First Detection of Molecules with Formal C≡Si Triple Bonds
Autor: Karni, Miriam ; Apeloig, Yitzhak ; Schröder, Detlef ; Zummack, Waltraud ; Rabezzana, Roberto ; Schwarz, Helmut
Assuntos: Ab initio calculations ; Mass spectrometry ; Silicon ; Silynes
É parte de: Angewandte Chemie (International ed.), 1999-02, Vol.38 (3), p.331-335
Notas: ark:/67375/WNG-NZNBP2VN-7
ArticleID:ANIE331
istex:B7314501735987C5ABE83FFDBBE77BEFE9D652A0
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Descrição: Neutralization of [C,H,Si,X] .+ radical cations (X=F, Cl) in conjunction with electronic structure calculations provides the first experimental evidence for the formation of the neutral silynes HC≡SiF and HC≡SiCl, which have nonlinear structures (see picture).
Editor: Weinheim: WILEY-VCH Verlag GmbH
Idioma: Inglês

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