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1:1 and 1:2 Inclusion Complexes of Di-tert-butyl l-tartrate with α-Cyclodextrin: A Diffusion Study

Mangiapia, Gaetano ; Sartorio, Roberto

Journal of solution chemistry, 2014-02, Vol.43 (1), p.186-205 [Periódico revisado por pares]

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Título:
1:1 and 1:2 Inclusion Complexes of Di-tert-butyl l-tartrate with α-Cyclodextrin: A Diffusion Study
Autor: Mangiapia, Gaetano ; Sartorio, Roberto
Assuntos: Chemical equilibrium ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Diffusion ; Diffusion coefficient ; Geochemistry ; Inclusion complexes ; Inclusions ; Industrial Chemistry/Chemical Engineering ; Inorganic Chemistry ; Interferometry ; Oceanography ; Physical Chemistry
É parte de: Journal of solution chemistry, 2014-02, Vol.43 (1), p.186-205
Notas: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Descrição: The diffusion properties at two overall compositions of a ternary aqueous system containing α-cyclodextrin and a double-functional guest molecule, namely di- tert -butyl l -tartrate, have been studied by means of the Gouy interferometry. The experimental data are interpreted in terms of two independent chemical equilibria involving inclusion compounds. The elements of the diffusion coefficient matrix have been expressed as functions of the two equilibrium constants as well as of the diffusivities of the actual species occurring in solution. The reliability of the diffusion coefficients obtained through the Fujita–Gosting–Revzin procedure is also discussed in terms of its dependence on the composition of solutions used in the Gouy experiments.
Editor: Boston: Springer US
Idioma: Inglês

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