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Acridinium-Based Photocatalysts: A Sustainable Option in Photoredox Catalysis

Joshi-Pangu, Amruta ; Lévesque, François ; Roth, Hudson G ; Oliver, Steven F ; Campeau, Louis-Charles ; Nicewicz, David ; DiRocco, Daniel A

Journal of organic chemistry, 2016-08, Vol.81 (16), p.7244-7249 [Periódico revisado por pares]

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Título:
Acridinium-Based Photocatalysts: A Sustainable Option in Photoredox Catalysis
Autor: Joshi-Pangu, Amruta ; Lévesque, François ; Roth, Hudson G ; Oliver, Steven F ; Campeau, Louis-Charles ; Nicewicz, David ; DiRocco, Daniel A
É parte de: Journal of organic chemistry, 2016-08, Vol.81 (16), p.7244-7249
Notas: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Descrição: The emergence of visible light photoredox catalysis has enabled the productive use of lower energy radiation, leading to highly selective reaction platforms. Polypyridyl complexes of iridium and ruthenium have served as popular photocatalysts in recent years due to their long excited state lifetimes and useful redox windows, leading to the development of diverse photoredox-catalyzed transformations. The low abundances of Ir and Ru in the earth’s crust and, hence, cost make these catalysts nonsustainable and have limited their application in industrial-scale manufacturing. Herein, we report a series of novel acridinium salts as alternatives to iridium photoredox catalysts and show their comparability to the ubiquitous [Ir(dF-CF3-ppy)2(dtbpy)](PF6).
Editor: United States: American Chemical Society
Idioma: Inglês

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