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Platforms for Stable Carbon‐Centered Radicals

Kato, Kenichi ; Osuka, Atsuhiro

Angewandte Chemie International Edition, 2019-07, Vol.58 (27), p.8978-8986 [Periódico revisado por pares]

Germany: Wiley Subscription Services, Inc

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  • Título:
    Platforms for Stable Carbon‐Centered Radicals
  • Autor: Kato, Kenichi ; Osuka, Atsuhiro
  • Assuntos: Carbon ; electronic structure ; Functional materials ; fused-ring systems ; magnetic properties ; materials science ; Platforms ; Radicals
  • É parte de: Angewandte Chemie International Edition, 2019-07, Vol.58 (27), p.8978-8986
  • Notas: ObjectType-Article-2
    SourceType-Scholarly Journals-1
    ObjectType-Feature-3
    content type line 23
    ObjectType-Review-1
  • Descrição: Organic radicals can potentially play important roles in functional materials owing to an unpaired electron, but they are usually highly reactive and difficult to use. Therefore, stabilization of organic radicals is important. Among organic radicals, carbon‐centered radicals are promising because of their trivalent nature, which enables structural diversity and elaborate designs, but they are also less stable because of the reactivities towards carbon–carbon bond formation and atmospheric oxygen. Recently, stable carbon‐centered radicals across diverse molecular platforms have been increasingly explored. This Minireview highlights these newly explored, stable carbon‐centered radicals, with a focus on porphyrinoid‐stabilized radicals because of their remarkable spin delocalization abilities. Spin control: Stable carbon‐centered radicals have been extensively developed as attractive building blocks for molecule‐based materials because of their structural diversity and tunable spin characteristics. This Minireview describes the electronic structures and stabilities of these radicals, with a focus on the developments within the last decade.
  • Editor: Germany: Wiley Subscription Services, Inc
  • Idioma: Inglês
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  • Realização: ABCD-USP USP   Logos de Redes Sociais: Freepik

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