skip to main content
Idioma:
Primo Search
Clear Search Box
Search in: Busca Geral
Busca Avançada
Busca por Índices

Tuning Photoluminescent Properties of Silver(I)-Based Coordination Networks through their Supramolecular Interactions

Matos, Catiúcia R. M. O ; Monteiro, Flávia G. A ; Miranda, Fabio da S ; Pinheiro, Carlos B ; Bond, Andrew D ; Ronconi, Célia M

Crystal growth & design, 2017-11, Vol.17 (11), p.5965-5974 [Periódico revisado por pares]

American Chemical Society

Texto completo disponível

Citações Citado por
  • Título:
    Tuning Photoluminescent Properties of Silver(I)-Based Coordination Networks through their Supramolecular Interactions
  • Autor: Matos, Catiúcia R. M. O ; Monteiro, Flávia G. A ; Miranda, Fabio da S ; Pinheiro, Carlos B ; Bond, Andrew D ; Ronconi, Célia M
  • É parte de: Crystal growth & design, 2017-11, Vol.17 (11), p.5965-5974
  • Descrição: Eight novel luminescent silver­(I)-based coordination networks have been self-assembled from two flexible dicyanomethylene ligands bearing diethylene (L1) and triethylene glycol (L2) spacers and silver salts (AgClO4 or AgBF4) in dichloromethane/toluene or dichloromethane/benzene solvents. Single-crystal X-ray diffraction reveals a variety of geometries around the silver­(I) ion, resulting in mono-, bi-, and tetranuclear networks with rare topologies. The coordination networks show two-dimensional architectures through coordination of the cyano and glycolic groups to the silver­(I) ions. The three-dimensional supramolecular arrangement is formed through weak π···π and Ag···π interactions as well as hydrogen bonds between water molecules and ClO4 – and BF4 – counterions. The silver­(I)-based coordination networks display green to yellow emissions in the solid state, with quantum yields (Φem) varying from 1.1 to 8.5%. The emission properties are attributed to intraligand charge transfer and metal-perturbed intraligand transitions. Supramolecular interactions, such as Ag···π and π···π interactions, play an important role in the photophysical properties of these compounds.
  • Editor: American Chemical Society
  • Idioma: Inglês
Voltar para lista de resultados

  • Realização: ABCD-USP USP   Logos de Redes Sociais: Freepik

Buscando em bases de dados remotas. Favor aguardar.