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Preparation of Graphene-Incorporated Chitosan-Polyvinyl Alcohol Composite Film Loaded with Copper-1-(2-Pyridylazo)-2-naphthol Complex and Its Application to Monitor Shrimp Freshness

GUO Yaping, CHEN Linmin, CHEN Quansheng, CHEN Xiaomei

Shípĭn kēxué, 2023-04, Vol.44 (8), p.330-336 [Periódico revisado por pares]

China Food Publishing Company

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  • Título:
    Preparation of Graphene-Incorporated Chitosan-Polyvinyl Alcohol Composite Film Loaded with Copper-1-(2-Pyridylazo)-2-naphthol Complex and Its Application to Monitor Shrimp Freshness
  • Autor: GUO Yaping, CHEN Linmin, CHEN Quansheng, CHEN Xiaomei
  • Assuntos: 1-(2-pyridylazo)-2-naphthol copper (ii); freshness; shrimp
  • É parte de: Shípĭn kēxué, 2023-04, Vol.44 (8), p.330-336
  • Descrição: A colorimetric composite film (Cu-PAN@G-CS/PVA) for the detection of H2S in shrimp meat by indicator displacement was prepared by tape casting method using copper (II)-1-(2-pyridylazo)-2-naphthol complex (Cu-PAN) as a H2S-sensitive material, chitosan (CS) combined with polyvinyl alcohol (PVA) as a film-forming material and graphene as a sensitizing material. The morphology and functional groups of Cu-PAN@G-CS/PVA were investigated by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR), and the sensing performance to H2S was examined by ultraviolet-visible (UV-vis) absorption spectroscopy. Experimental results showed that the color of the Cu-PAN@G-CS/PVA film changed from purplish red to yellow with increasing H2S concentration. This film was used to monitor the freshness of Penaeus chinensis stored at 4 or 25 ℃. It was shown that the trend of the color difference value (ΔE) of the Cu-PAN@G-CS/PVA film had a good correlation with the total volatile basic nitrogen (TVB-N) content of the sample. Therefore, the Cu-PAN@G-CS/PVA film could accurately and rapidly indicate the freshness of P. chinensis, which may provide a reference for the development of intelligent packaging of aquatic products.
  • Editor: China Food Publishing Company
  • Idioma: Inglês
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  • Realização: ABCD-USP USP   Logos de Redes Sociais: Freepik

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