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ALD/MLD coating of patterned vertically aligned carbon nanotube micropillars with Fe-NH 2 TP hybrids

Silva, R M ; Rocha, J ; Silva, R F

Nanoscale, 2023-06, Vol.15 (24), p.10423-10429 [Periódico revisado por pares]

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Título:
ALD/MLD coating of patterned vertically aligned carbon nanotube micropillars with Fe-NH 2 TP hybrids
Autor: Silva, R M ; Rocha, J ; Silva, R F
É parte de: Nanoscale, 2023-06, Vol.15 (24), p.10423-10429
Descrição: The creation of nanoscale organic-inorganic hybrid coatings with uniform architecture and high surface area, while maintaining their structural and morphological integrity, remains a significant challenge in the field. In this study, we present a novel solution, by utilizing Atomic/Molecular Layer Deposition (ALD/MLD) to coat patterned vertically aligned carbon nanotube micropillars with a conformal amorphous layer of Fe-NH TP, which is a trivalent iron complex complexed with 2-amino terephthalate. The effectiveness of the coating is verified through multiple analytical techniques, including high-resolution transmission electron microscopy, scanning transmission electron microscopy, grazing incidence X-ray diffraction, and Fourier transform infrared spectroscopy. The Fe-NH TP hybrid film exhibits hydrophobic properties, as confirmed by water contact angle measurements. Our findings contribute to advancing the understanding of how to grow high-quality one-dimensional materials using ALD/MLD and hold promise for future research in this area.
Editor: England
Idioma: Inglês

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