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1,1′-Carbonyldiimidazole mediates the synthesis of N-substituted imidazole derivatives from Morita–Baylis–Hillman adducts

Rodrigues, Manoel T. ; Santos, Marilia S. ; Santos, Hugo ; Coelho, Fernando

Tetrahedron letters, 2014-01, Vol.55 (1), p.180-183 [Periódico revisado por pares]

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Título:
1,1′-Carbonyldiimidazole mediates the synthesis of N-substituted imidazole derivatives from Morita–Baylis–Hillman adducts
Autor: Rodrigues, Manoel T. ; Santos, Marilia S. ; Santos, Hugo ; Coelho, Fernando
Assuntos: Diastereoselective ; Imidazole ; Ionic liquids ; Michael reaction ; Morita–Baylis–Hillman
É parte de: Tetrahedron letters, 2014-01, Vol.55 (1), p.180-183
Descrição: In this Letter, we describe a simple and straightforward method for the synthesis of N-substituted imidazole derivatives. 1,1-carbonyldiimidazole mediates the process, which requires no activation group step. We obtained imidazole derivatives in high yields and with short reaction times. To demonstrate the synthetic significance of the aforementioned compounds, we also describe the synthesis of novel ionic liquids from these derivatives.
Editor: Elsevier Ltd
Idioma: Inglês

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