skip to main content
Idioma:
Primo Search
Clear Search Box
Search in: Busca Geral
Busca Avançada
Busca por Índices

Delocalization and occupancy effects of 5f orbitals in plutonium intermetallics using L sub(3)-edge resonant X-ray emission spectroscopy

Booth, CH ; Medling, SA ; Jiang, Yu ; Bauer, ED ; Tobash, PH ; Mitchell, J N ; Veirs, D K ; Wall, MA ; Allen, P G ; Kas, J J ; Sokaras, D ; Nordlund, D ; Weng, T-C

Journal of electron spectroscopy and related phenomena, 2014-06, Vol.194, p.57-65 [Periódico revisado por pares]

Texto completo disponível

Citações Citado por
  • Título:
    Delocalization and occupancy effects of 5f orbitals in plutonium intermetallics using L sub(3)-edge resonant X-ray emission spectroscopy
  • Autor: Booth, CH ; Medling, SA ; Jiang, Yu ; Bauer, ED ; Tobash, PH ; Mitchell, J N ; Veirs, D K ; Wall, MA ; Allen, P G ; Kas, J J ; Sokaras, D ; Nordlund, D ; Weng, T-C
  • Assuntos: Actinides ; Bonding ; Emission spectroscopy ; Mathematical analysis ; Occupation ; Orbitals ; Spectra ; X-rays
  • É parte de: Journal of electron spectroscopy and related phenomena, 2014-06, Vol.194, p.57-65
  • Notas: ObjectType-Article-1
    SourceType-Scholarly Journals-1
    content type line 23
    ObjectType-Feature-2
  • Descrição: Although actinide (An) L sub(3)-edge X-ray absorption near-edge structure (XANES) spectroscopy has been very effective in determining An oxidation states in insulating, ionically bonded materials, such as in certain coordination compounds and mineral systems, the technique fails in systems featuring more delocalized 5f orbitals, especially in metals. Recently, actinide L sub(3)-edge resonant X-ray emission spectroscopy (RXES) has been shown to be an effective alternative. This technique is further demonstrated here using a parameterized partial unoccupied density of states method to quantify both occupancy and delocalization of the 5f orbital in alpha -Pu, delta -Pu, PuCoGa sub(5), PuCoIn sub(5), and PuSb sub(2). These new results, supported by FEFF calculations, highlight the effects of strong correlations on RXES spectra and the technique's ability to differentiate between f-orbital occupation and delocalization.
  • Idioma: Inglês;Francês;Alemão
Voltar para lista de resultados
Ir para página anteriorAnterior Resultado  8 AvançarIr para próxima página

  • Realização: ABCD-USP USP   Logos de Redes Sociais: Freepik

Buscando em bases de dados remotas. Favor aguardar.