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Photoredox Catalysis in Organic Chemistry

Shaw, Megan H ; Twilton, Jack ; MacMillan, David W. C

Journal of organic chemistry, 2016-08, Vol.81 (16), p.6898-6926 [Periódico revisado por pares]

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Título:
Photoredox Catalysis in Organic Chemistry
Autor: Shaw, Megan H ; Twilton, Jack ; MacMillan, David W. C
É parte de: Journal of organic chemistry, 2016-08, Vol.81 (16), p.6898-6926
Notas: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Descrição: In recent years, photoredox catalysis has come to the forefront in organic chemistry as a powerful strategy for the activation of small molecules. In a general sense, these approaches rely on the ability of metal complexes and organic dyes to convert visible light into chemical energy by engaging in single-electron transfer with organic substrates, thereby generating reactive intermediates. In this Perspective, we highlight the unique ability of photoredox catalysis to expedite the development of completely new reaction mechanisms, with particular emphasis placed on multicatalytic strategies that enable the construction of challenging carbon–carbon and carbon–heteroatom bonds.
Editor: United States: American Chemical Society
Idioma: Inglês

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