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Comparison of Reorganization Energies for Intra- and Intermolecular Electron Transfer

Imahori, Hiroshi ; Yamada, Hiroko ; Guldi, Dirk M. ; Endo, Yoshito ; Shimomura, Akihisa ; Kundu, Santi ; Yamada, Koji ; Okada, Tadashi ; Sakata, Yoshiteru ; Fukuzumi, Shunichi

Angewandte Chemie (International ed.), 2002-07, Vol.41 (13), p.2344-2347 [Periódico revisado por pares]

Weinheim: WILEY-VCH Verlag GmbH

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  • Título:
    Comparison of Reorganization Energies for Intra- and Intermolecular Electron Transfer
  • Autor: Imahori, Hiroshi ; Yamada, Hiroko ; Guldi, Dirk M. ; Endo, Yoshito ; Shimomura, Akihisa ; Kundu, Santi ; Yamada, Koji ; Okada, Tadashi ; Sakata, Yoshiteru ; Fukuzumi, Shunichi
  • Assuntos: donor-acceptor systems ; electron transfer ; fullerenes ; photosynthesis ; porphyrinoids
  • É parte de: Angewandte Chemie (International ed.), 2002-07, Vol.41 (13), p.2344-2347
  • Notas: This work was supported by COE, Grant-in-Aid for Scientific Research, Specially Promoted Research (No. 10102007), and the Development of Innovative Technology (No. 12310) from Ministry of Education, Sports, Culture, Science and Technology, Japan and by the Office of Basic Energy Sciences of the U.S. Department of Energy. This is document NDRL-4379 from the Notre Dame Radiation Laboratory.
    ArticleID:ANIE2344
    ark:/67375/WNG-RXB6NWXH-3
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    This work was supported by COE, Grant‐in‐Aid for Scientific Research, Specially Promoted Research (No. 10102007), and the Development of Innovative Technology (No. 12310) from Ministry of Education, Sports, Culture, Science and Technology, Japan and by the Office of Basic Energy Sciences of the U.S. Department of Energy. This is document NDRL‐4379 from the Notre Dame Radiation Laboratory.
    ObjectType-Article-1
    SourceType-Scholarly Journals-1
    ObjectType-Feature-2
    content type line 23
  • Descrição: Do electrons prefer to visit planes or spheres? Reorganization energies for intramolecular electron transfer involving a 3D acceptor (C60) and a 2D acceptor (NIm; see scheme) have been determined. Comparison of reorganization energies for the intra‐ versus intermolecular electron transfer has provided, for the first time, valuable insight into the intrinsic reorganization energies relating to different molecular shapes.
  • Editor: Weinheim: WILEY-VCH Verlag GmbH
  • Idioma: Inglês
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