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A classical [V 10 O 28 ] 6− anion templated high-nuclearity silver thiolate cluster

Li, Li ; Zhu, Yanjie ; Han, Baoliang ; Wang, Qiongyi ; Zheng, Luming ; Feng, Lei ; Sun, Di ; Wang, Zhi

Chemical communications (Cambridge, England), 2022-08, Vol.58 (66), p.9234-9237 [Periódico revisado por pares]

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Título:
A classical [V 10 O 28 ] 6− anion templated high-nuclearity silver thiolate cluster
Autor: Li, Li ; Zhu, Yanjie ; Han, Baoliang ; Wang, Qiongyi ; Zheng, Luming ; Feng, Lei ; Sun, Di ; Wang, Zhi
Assuntos: Clusters ; Photoelectric effect ; Photoelectricity
É parte de: Chemical communications (Cambridge, England), 2022-08, Vol.58 (66), p.9234-9237
Notas: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Descrição: Polyoxovanadates (POVs) as templates are still scarcely observed in silver clusters. Herein, the largest known POV-based silver cluster (Ag50) was synthesized, which is a core–shell conformation composed of the in situ generated classical [V 10 O 28 ] 6− core and Ag 50 shell, constrained by the S- and O-donor ligands with a specific distribution. Such {V 10 O 28 @Ag 50 } structure displays geometric inheritance from the D 2h symmetric decavanadate to the silver skeleton. The solution behavior, solid-state stability and photoelectric properties are discussed in detail. This work provides enlightenment for the further construction of POV-templated high-nuclearity silver clusters.
Editor: Cambridge: Royal Society of Chemistry
Idioma: Inglês

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