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Product Divergence in Coinage-Metal-Catalyzed Reactions of π-Rich Compounds

Boyle, Joshua William ; Zhao, Yichao ; Chan, Philip Wai Hong

Synthesis (Stuttgart), 2018-04, Vol.50 (7), p.1402-1416 [Periódico revisado por pares]

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Título:
Product Divergence in Coinage-Metal-Catalyzed Reactions of π-Rich Compounds
Autor: Boyle, Joshua William ; Zhao, Yichao ; Chan, Philip Wai Hong
Assuntos: short review
É parte de: Synthesis (Stuttgart), 2018-04, Vol.50 (7), p.1402-1416
Descrição: Abstract This short review aims to summarize how the product outcome of reactions of a common starting material can sometimes be controlled by the judicious choice of copper, silver or gold as the catalyst. It highlights the different reactivities observed in the functional group transformations of π-rich substrates mediated by the three group 11 metal salts. 1 Introduction 2 Reactions of Propargyl Amines, Esters and Their Derivatives 3 Reactions of Phenylacetylene Derivatives 4 Reactions of π-Rich Alcohols and Ethers 5 Indolyl Cyclopropene and Alkynone Rearrangements 6 Reactions Involving Metal-Carbene and Metal-Carbenoid Intermediates 7 Conclusion
Editor: Stuttgart · New York: Georg Thieme Verlag
Idioma: Inglês

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