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Macrocyclic High-Spin (S=2) Molecule: Spin Identification of a Sterically Rigid Metacyclophane-Based Nitroxide Tetraradical by Two-Dimensional Electron Spin Transient Nutation Spectroscopy

Sawai, Takatoshi ; Sato, Kazunobu ; Ise, Tomoaki ; Shiomi, Daisuke ; Toyota, Kazuo ; Morita, Yasushi ; Takui, Takeji

Angewandte Chemie, 2008-05, Vol.120 (21), p.4052-4054 [Periódico revisado por pares]

Weinheim: WILEY-VCH Verlag

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  • Título:
    Macrocyclic High-Spin (S=2) Molecule: Spin Identification of a Sterically Rigid Metacyclophane-Based Nitroxide Tetraradical by Two-Dimensional Electron Spin Transient Nutation Spectroscopy
  • Autor: Sawai, Takatoshi ; Sato, Kazunobu ; Ise, Tomoaki ; Shiomi, Daisuke ; Toyota, Kazuo ; Morita, Yasushi ; Takui, Takeji
  • Assuntos: EPR-Spektroskopie ; High-Spin-Systeme ; Makrocyclen ; Radikale ; Transiente Elektronenspin-Nutation
  • É parte de: Angewandte Chemie, 2008-05, Vol.120 (21), p.4052-4054
  • Notas: This work has been supported by Grants-in-Aids for Scientific Research from the Ministry of Education, Sports, Culture, Science and Technology (Japan). One of the authors (T.S.) acknowledges Research Fellowships of the Japan Society for the Promotion of Science for Young Scientists.
    ArticleID:ANGE200705583
    Research Fellowships of the Japan Society for the Promotion of Science for Young Scientists
    istex:DFE1C1DFB80CA0EECD3BFEDEE67B01B9047BC919
    Grants-in-Aids for Scientific Research from the Ministry of Education, Sports, Culture, Science and Technology (Japan)
    ark:/67375/WNG-PDWZ63FV-P
    This work has been supported by Grants‐in‐Aids for Scientific Research from the Ministry of Education, Sports, Culture, Science and Technology (Japan). One of the authors (T.S.) acknowledges Research Fellowships of the Japan Society for the Promotion of Science for Young Scientists.
  • Descrição: Ein Spin‐Quintett: Die elektronische und Molekülstruktur des von einem Metacyclophan abgeleiteten Spin‐Quintett‐Tetraradikals 1 mit sterisch bedingter starrer Struktur und kleinen Feinstrukturparametern wird charakterisiert. Mit Puls‐ESR‐basierter 2D‐Elektronenspin‐Nutationsspektroskopie wurde die Spinmultiplizität von 1 zweifelsfrei ermittelt sowie seine Feinstrukturparameter und g‐Werte erhalten.
  • Editor: Weinheim: WILEY-VCH Verlag
  • Idioma: Inglês;Alemão

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