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Porphyrins in 1,3-Dipolar Cycloaddition Reactions. Synthesis of New Porphyrin−Chlorin and Porphyrin−Tetraazachlorin Dyads

Silva, Ana M. G ; Lacerda, Paula S. S ; Tomé, Augusto C ; Neves, Maria G. P. M. S ; Silva, Artur M. S ; Cavaleiro, José A. S ; Makarova, Elena A ; Lukyanets, Evgeny A

Journal of organic chemistry, 2006-10, Vol.71 (22), p.8352-8356 [Periódico revisado por pares]

Washington, DC: American Chemical Society

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  • Título:
    Porphyrins in 1,3-Dipolar Cycloaddition Reactions. Synthesis of New Porphyrin−Chlorin and Porphyrin−Tetraazachlorin Dyads
  • Autor: Silva, Ana M. G ; Lacerda, Paula S. S ; Tomé, Augusto C ; Neves, Maria G. P. M. S ; Silva, Artur M. S ; Cavaleiro, José A. S ; Makarova, Elena A ; Lukyanets, Evgeny A
  • É parte de: Journal of organic chemistry, 2006-10, Vol.71 (22), p.8352-8356
  • Notas: ark:/67375/TPS-SM8GVLJF-P
    istex:E3CAE349EA376D23C998BE77C8A3514B99227B58
    ObjectType-Article-1
    SourceType-Scholarly Journals-1
    ObjectType-Feature-2
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  • Descrição: N-(Porphyrin-2-ylmethyl)glycine was synthesized and used as precursor of azomethine ylide, which was trapped with several dipolarophiles. The reaction of that azomethine ylide with dimethyl fumarate afforded the expected adduct. However, with 1,4-benzo- and 1,4-naphthoquinones only dehydrogenated adducts were isolated. Also, the reaction of that ylide with meso-tetrakis(pentafluorophenyl)porphyrin and tetraazaporphine allowed access to novel porphyrin−chlorin and porphyrin−tetraazachlorin dyads.
  • Editor: Washington, DC: American Chemical Society
  • Idioma: Inglês;Russo

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