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Biocompatible Photoinduced Alkylation of Dehydroalanine for the Synthesis of Unnatural α‑Amino Acids

Delgado, José A. C ; Correia, José T. M ; Pissinati, Emanuele F ; Paixão, Márcio W

Organic letters, 2021-07, Vol.23 (13), p.5251-5255 [Periódico revisado por pares]

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Título:
Biocompatible Photoinduced Alkylation of Dehydroalanine for the Synthesis of Unnatural α‑Amino Acids
Autor: Delgado, José A. C ; Correia, José T. M ; Pissinati, Emanuele F ; Paixão, Márcio W
É parte de: Organic letters, 2021-07, Vol.23 (13), p.5251-5255
Notas: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Descrição: A site-selective alkylation of dehydroalanine to access protected unnatural amino acids is described. The protocol is characterized by the wide nature of alkyl radicals employed, mild conditions, and functional group compatibility. This protocol is further extended to access peptides, late-stage functionalization of pharmaceuticals, and enantioenriched amino acids.
Editor: American Chemical Society
Idioma: Inglês

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