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Structure and reactivity in neutral organic electron donors derived from 4-dimethylaminopyridine

Garnier, Jean ; Kennedy, Alan R ; Berlouis, Leonard E A ; Turner, Andrew T ; Murphy, John A

Beilstein journal of organic chemistry, 2010-07, Vol.6 (1), p.73 [Periódico revisado por pares]

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Título:
Structure and reactivity in neutral organic electron donors derived from 4-dimethylaminopyridine
Autor: Garnier, Jean ; Kennedy, Alan R ; Berlouis, Leonard E A ; Turner, Andrew T ; Murphy, John A
Assuntos: 4-DMAP ; Chemistry ; dication ; electron donor ; electron transfer ; Full Research Paper ; radical cation ; redox ; reduction
É parte de: Beilstein journal of organic chemistry, 2010-07, Vol.6 (1), p.73
Notas: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Descrição: The effects on the redox properties of modifying the molecular skeleton of neutral bis-2-(4-dimethylamino)pyridinylidene electron donors, derived from 4-dimethylaminopyridine (4-DMAP), have been explored, by varying two parameters: (i) the length of a polymethylene chain linking the two pyridine-derived rings and (ii) the nature of the nitrogen substituents on the 4 and 4' positions of the precursor pyridines. Restricting the bridge length to two methylene units significantly altered the redox profile, while changes in the nitrogen-substituents at the 4 and 4' positions led to only slight changes in the redox potentials.
Editor: Germany: Beilstein-Institut
Idioma: Inglês

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