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Bound ("Glassy") Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black

Kondyurin, Alexey V ; Eliseeva, Anastasia Yu ; Svistkov, Alexander L

Materials, 2018-10, Vol.11 (10), p.1992 [Periódico revisado por pares]

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Título:
Bound ("Glassy") Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black
Autor: Kondyurin, Alexey V ; Eliseeva, Anastasia Yu ; Svistkov, Alexander L
Assuntos: carbon black ; crosslinking ; ellipsometry ; free radicals ; FTIR ; glassy layer ; graphite ; rubber
É parte de: Materials, 2018-10, Vol.11 (10), p.1992
Notas: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Descrição: A model of rubber with a cross-linked rubber layer on a carbon black filler has been proposed. The cross-links are the result of free radical reactions generated by carbon atoms with unpaired electrons at the edge of graphitic sheets in a carbon black filler. The experimental study of the cross-linking reactions in polyisoprene was done on a flat carbonized surface after ion beam implantation. The cross-linking process in the polyisoprene macromolecules between two particles was simulated. The model with a cross-linked rubber layer on a carbon filler as a "glassy layer" explains the mechanical properties of the rubber materials.
Editor: Switzerland: MDPI
Idioma: Inglês

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