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Structural characterization of FePdP: stabilization of a new polytype of the MM'X series

Artigas, M. ; Bacmann, M. ; Fruchart, D. ; Wolfers, P. ; Fruchart, R.

Journal of alloys and compounds, 1991-10, Vol.176 (1), p.105-114 [Periódico revisado por pares]

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Título:
Structural characterization of FePdP: stabilization of a new polytype of the MM'X series
Autor: Artigas, M. ; Bacmann, M. ; Fruchart, D. ; Wolfers, P. ; Fruchart, R.
Assuntos: Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Halides, chalcogenides and analogous compounds of group vb ; Inorganic compounds ; Physics ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids
É parte de: Journal of alloys and compounds, 1991-10, Vol.176 (1), p.105-114
Descrição: FePdP crystallizes in the space group P 6 2 m with unit cell parameters a=12.055(2) A ̊ and c=3.636(2) A ̊ . It is a new type of superstructure of the Fe 2P type. However, the metal sites display different degrees of atomic disorder. The structure is analysed in terms of the phosphorus coordination polyhedra of the metal atoms, which allows it to be included among the polytypic series of MM'X (M and M', transition metals; X≊ P , As, Si, Ge,...) phases.
Editor: Lausanne: Elsevier B.V
Idioma: Inglês

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