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HIGH ENERGY OXIDIZERS

Christe, Karl O ; Guertin, J P ; Pavlath, A E

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Título:
HIGH ENERGY OXIDIZERS
Autor: Christe, Karl O ; Guertin, J P ; Pavlath, A E
Assuntos: ALKALI METAL COMPOUNDS ; CESIUM COMPOUNDS ; CHLORATES ; DENSITY ; ELECTRICITY ; FLUORIDES ; FLUOROCHLORIDES ; INFRARED SPECTRA ; Inorganic Chemistry ; IONS ; MOLECULAR STRUCTURE ; NITROGEN ; OXIDIZERS ; RUBIDIUM ; Solid Rocket Propellants ; SOLIDS ; SOLUTIONS(MIXTURES) ; X RAY DIFFRACTION
Notas: DTIC AND NTIS
Descrição: Infrared and conductivity measurements show that MClF4 (where M is NO, Rb, or Cs) is ionic in the solid state and in solution, respectively. A square-planar structure (point group D(4h)) is assigned to the ClF4(-) anion in Rb(+) ClF4(-) and Cs(+) ClF4(-). For the ClF4(-) anion in NO(+) ClF4(-) the low-temperature infrared measurement indicates a lower symmetry (at least as low as point group D(2h)). A vacuum line, which will enable running glow-discharge reactions at low temperatures and reduced pressures, was designed and built. Density measurements on the alkali metal difluorochlorates (I) indicate that the X-ray patterns given in the preceding Quarterly Report are probably due to small amounts of alkali metal bifluorides, present as impurities. See also AD0612661.
Data de criação/publicação: 1965
Idioma: Inglês

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