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Crystal Growth and Phase Equilibria in the BaB2O4−NaF System

Bekker, T. B ; Kokh, A. E ; Kononova, N. G ; Fedorov, P. P ; Kuznetsov, S. V

Crystal growth & design, 2009-09, Vol.9 (9), p.4060-4063 [Periódico revisado por pares]

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Título:
Crystal Growth and Phase Equilibria in the BaB2O4−NaF System
Autor: Bekker, T. B ; Kokh, A. E ; Kononova, N. G ; Fedorov, P. P ; Kuznetsov, S. V
É parte de: Crystal growth & design, 2009-09, Vol.9 (9), p.4060-4063
Descrição: The phase formation in the BaB2O4- NaF system has been studied by the methods of solid-state synthesis, visual polythermal analysis, spontaneous crystallization on platinum loop and differential thermal analysis. A new version of BaB2O4−NaF phase diagram has been obtained as the result of comprehensive investigations. Conditions for primary crystallization of the new compound Ba2Na3(B3O6)2F (hexagonal system, P63/m, a = 7,346(1) Å, c = 12,637(2) Å) have been determined. Bulk crystals of Ba2Na3(B3O6)2F have been grown. An absorption edge in the UV spectrum of the above compound has been characterized.
Editor: American Chemical Society
Idioma: Inglês

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