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Boryllithium: Isolation, Characterization, and Reactivity as a Boryl Anion

Segawa, Yasutomo ; Yamashita, Makoto ; Nozaki, Kyoko

Science (American Association for the Advancement of Science), 2006-10, Vol.314 (5796), p.113-115 [Periódico revisado por pares]

Washington, DC: American Association for the Advancement of Science

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Título:
Boryllithium: Isolation, Characterization, and Reactivity as a Boryl Anion
Autor: Segawa, Yasutomo ; Yamashita, Makoto ; Nozaki, Kyoko
Assuntos: Anions ; Atoms ; B derivatives ; Boron ; Carbenes ; Chemical bonds ; Chemical compounds ; Chemistry ; Covalent bonds ; Crystal structure ; Crystallography ; Exact sciences and technology ; Lithium ; Molecules ; Nuclear magnetic resonance ; Organic chemistry ; Organometalloidal and organometallic compounds ; Preparations and properties ; Salts
É parte de: Science (American Association for the Advancement of Science), 2006-10, Vol.314 (5796), p.113-115
Notas: http://www.scienceonline.org/
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Descrição: Nucleophilic, anionic boryl compounds are long-sought but elusive species. We report that reductive cleavage of the boron-bromine bond in N,N'-bis(2,6-diisopropylphenyl)-2-bromo-2,3-dihydro-1H-1,3,2-diazaborole by lithium naphthalenide afforded the corresponding boryllithium, which is isoelectronic with an N-heterocyclic carbene. The structure of the boryllithium determined by x-ray crystallography was consistent with sp2 boron hybridization and revealed a boron-lithium bond length of 2.291 ± 0.006 angstroms. The structural similarity between this compound and the calculated free boryl anion suggests that the boron atom has an anionic charge. The 11B nuclear magnetic resonance spectrum also supports the boryl anion character. Moreover, the compound behaves as an efficient base and nucleophile in its reactions with electrophiles such as water, methyl trifluoromethanesulfonate, 1-chlorobutane, and benzaldehyde.
Editor: Washington, DC: American Association for the Advancement of Science
Idioma: Inglês

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Boryllithium: Isolation, Characterization, and Reactivity as a Boryl Anion

Segawa, Yasutomo ; Yamashita, Makoto ; Nozaki, Kyoko

Washington, DC: American Association for the Advancement of Science

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