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Iron(II) Spin Crossover Complexes with 4,4'-Dipyridylethyne-Crystal Structures and Spin Crossover with Hysteresis

Dankhoff, Katja ; Lochenie, Charles ; Weber, Birgit

Molecules (Basel, Switzerland), 2020-01, Vol.25 (3), p.581 [Periódico revisado por pares]

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Título:
Iron(II) Spin Crossover Complexes with 4,4'-Dipyridylethyne-Crystal Structures and Spin Crossover with Hysteresis
Autor: Dankhoff, Katja ; Lochenie, Charles ; Weber, Birgit
Assuntos: Composite materials ; cooperative interactions ; Coordination polymers ; Crossovers ; Crystal structure ; Hydrogen bonds ; Hysteresis ; Hysteresis loops ; Imines ; Iron ; Ligands ; Polymers ; Room temperature ; schiff base ligand ; Scientific imaging ; Single crystals ; Solvents ; spin crossover
É parte de: Molecules (Basel, Switzerland), 2020-01, Vol.25 (3), p.581
Notas: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Descrição: Three new iron(II) 1D coordination polymers with cooperative spin crossover behavior showing thermal hysteresis loops were synthesized using N O Schiff base-like equatorial ligands and 4,4'-dipyridylethyne as a bridging, rigid axial linker. One of those iron(II) 1D coordination polymers showed a 73 K wide hysteresis below room temperature, which, upon solvent loss, decreased to a still remarkable 30 K wide hysteresis. Single crystal X-ray structures of two iron(II) coordination polymers and -dependent powder XRD patterns are discussed to obtain insight into the structure property relationship of those materials.
Editor: Switzerland: MDPI AG
Idioma: Inglês

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