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Glycerol Electro-Oxidation in Alkaline Medium with Pt-Fe/C Electrocatalysts Synthesized by the Polyol Method: Increased Selectivity and Activity Provided by Less Expensive Catalysts

Lima, Vanderlei S ; Almeida, Thiago S ; De Andrade, Adalgisa R

Nanomaterials (Basel, Switzerland), 2023-03, Vol.13 (7), p.1173 [Revista revisada por pares]

Switzerland: MDPI AG

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Glycerol Electro-Oxidation in Alkaline Medium with Pt-Fe/C Electrocatalysts Synthesized by the Polyol Method: Increased Selectivity and Activity Provided by Less Expensive Catalysts
Autor: Lima, Vanderlei S ; Almeida, Thiago S ; De Andrade, Adalgisa R
Materias: alkaline medium ; Alloys ; Biodiesel fuels ; Carbon ; Catalysts ; Electric properties ; electrocatalysis ; Electrocatalysts ; Electrochemistry ; Electrolysis ; Ethanol ; Glycerin ; Glycerol ; glycerol oxidation ; Heavy metals ; Iron ; Metals ; Methods ; Nanoparticles ; Oxidation ; Platinum ; Process parameters ; Pt-based catalyst ; Spectrum analysis ; Synthesis ; Ultrasonic imaging
Es parte de: Nanomaterials (Basel, Switzerland), 2023-03, Vol.13 (7), p.1173
Notas: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Descripción: We have investigated platinum catalysts containing iron as a modifier to obtain catalysts with superior electrocatalytic activity toward glycerol electro-oxidation in an alkaline medium. The electrocatalysts, supported on carbon Vulcan, were synthesized by the polyol method. The physicochemical characterization data showed that the metals were well distributed on the carbon support and had small particle size (2 nm). The Pt:Fe metal ratio differed from the nominal composition, indicating that reducing iron with platinum was difficult, even though some parameters of the synthesis process were changed. Electrochemical analyses revealed that PtFe/C was more active and stable than commercial Pt/C was, and analysis of the electrolysis by-products showed that iron addition to Pt/C boosted the glycerol conversion and selectivity for glyceric acid formation.
Editor: Switzerland: MDPI AG
Idioma: Inglés

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Glycerol Electro-Oxidation in Alkaline Medium with Pt-Fe/C Electrocatalysts Synthesized by the Polyol Method: Increased Selectivity and Activity Provided by Less Expensive Catalysts

Lima, Vanderlei S ; Almeida, Thiago S ; De Andrade, Adalgisa R

Switzerland: MDPI AG

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