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Carbon-Carbon Bond Cleavage by Strongly Electrophilic Boranes

Xu, Bao-Hua ; Kehr, Gerald ; Fröhlich, Roland ; Erker, Gerhard

Chemistry : a European journal, 2010-11, Vol.16 (42), p.12538-12540 [Periódico revisado por pares]

Weinheim: WILEY-VCH Verlag

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  • Título:
    Carbon-Carbon Bond Cleavage by Strongly Electrophilic Boranes
  • Autor: Xu, Bao-Hua ; Kehr, Gerald ; Fröhlich, Roland ; Erker, Gerhard
  • Assuntos: boranes ; carboboration ; Chemistry ; CC activation ; ring expansion
  • É parte de: Chemistry : a European journal, 2010-11, Vol.16 (42), p.12538-12540
  • Notas: ark:/67375/WNG-T11QPLP1-2
    istex:E2A3B766705CDB3C19D657ED4C47D28BD0006B5C
    Deutsche Forschungsgemeinschaft
    Fonds der Chemischen Industrie
    ArticleID:CHEM201002047
    X‐ray structure analyses.
    ObjectType-Article-1
    SourceType-Scholarly Journals-1
    ObjectType-Feature-2
    content type line 23
  • Descrição: Make and break: Strongly electrophilic boranes RB(C6F5)2 (R=Me, CH2CH2Ph) react with an aminodihydropentalene substrate by CC bond cleavage with concomitant borylene insertion to yield the ring‐enlarged zwitterionic borate/iminium product.
  • Editor: Weinheim: WILEY-VCH Verlag
  • Idioma: Inglês

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