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Mechanism of the Protonation of Ferrocenylacetic Acid by Perchloric Acid

Fomin, V. M. ; Shuklina, N. N.

Russian Journal of Physical Chemistry A, 2022, Vol.96 (5), p.1129-1133 [Periódico revisado por pares]

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Título:
Mechanism of the Protonation of Ferrocenylacetic Acid by Perchloric Acid
Autor: Fomin, V. M. ; Shuklina, N. N.
Assuntos: Brief Communications ; Cations ; Chemistry ; Chemistry and Materials Science ; Perchloric acid ; Physical Chemistry ; Protonation
É parte de: Russian Journal of Physical Chemistry A, 2022, Vol.96 (5), p.1129-1133
Descrição: Electron spectroscopy shows that the formation of ferrocenium cations upon the protonation of FcCH 2 COOH by perchloric acid in dioxane is a result of the redox isomerism of carbocation FcC + H 2 . The latter forms during the fragmentation of acyl ion FcCH 2 C + O, the primary product of protonation. The extreme nature of the dependence of the rate of accumulation of ferrocenium cations on the concentration of FcCH 2 COOH as a result of it reacting with FcC + H 2 distinguishes this process from those of the protonation of other derivatives of ferrocene.
Editor: Moscow: Pleiades Publishing
Idioma: Inglês

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