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Cooperative Bond Activation and Catalytic Reduction of Carbon Dioxide at a Group 13 Metal Center

Abdalla, Joseph A. B. ; Riddlestone, Ian M. ; Tirfoin, Rémi ; Aldridge, Simon

Angewandte Chemie, 2015-04, Vol.127 (17), p.5187-5191 [Periódico revisado por pares]

Weinheim: WILEY-VCH Verlag

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  • Título:
    Cooperative Bond Activation and Catalytic Reduction of Carbon Dioxide at a Group 13 Metal Center
  • Autor: Abdalla, Joseph A. B. ; Riddlestone, Ian M. ; Tirfoin, Rémi ; Aldridge, Simon
  • Assuntos: Activation ; Bindungsaktivierung ; Bonding ; Carbon dioxide ; Catalysts ; Chemistry ; Derivatives ; Gallium ; Hydrides ; Kohlendioxid ; Kooperative Reaktivität ; Ligands ; Methyl alcohol ; Reduction ; β-Diketiminat
  • É parte de: Angewandte Chemie, 2015-04, Vol.127 (17), p.5187-5191
  • Notas: EPSRC
    ArticleID:ANGE201500570
    ark:/67375/WNG-PDX6SZVJ-Z
    EPSRC (studentship: J.A.B.A.; NMSF, Swansea University; EP/L025000/1 and EP/K014714/1).
    istex:80F30382AF179AB1CE75A488C38600695106C3F7
    ObjectType-Article-1
    SourceType-Scholarly Journals-1
    ObjectType-Feature-2
    content type line 23
  • Descrição: A single‐component ambiphilic system capable of the cooperative activation of protic, hydridic and apolar HX bonds across a Group 13 metal/activated β‐diketiminato (Nacnac) ligand framework is reported. The hydride complex derived from the activation of H2 is shown to be a competent catalyst for the highly selective reduction of CO2 to a methanol derivative. To our knowledge, this process represents the first example of a reduction process of this type catalyzed by a molecular gallium complex. Ein ambiphiler Gruppe‐13‐Komplex wurde entwickelt, der zur kooperativen Aktivierung protischer, hydridischer und apolarer H‐X‐Bindungen befähigt ist. Der Hydridkomplex, der aus der Aktivierung von H2 entsteht, katalysiert die selektive Umwandlung von CO2 in ein Methanolderivat. Dies ist das erste Beispiel für solch eine durch einen molekularen Ga‐Komplex katalysierte Reduktion.
  • Editor: Weinheim: WILEY-VCH Verlag
  • Idioma: Inglês;Alemão
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  • Realização: ABCD-USP USP   Logos de Redes Sociais: Freepik

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