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Redical and Molecular Yields in the y-Irradiation of Liquid Methanol

Adams, G. E. ; Baxendale, J. H.

Journal of the American Chemical Society, 1958-08, Vol.80 (16) [Periódico revisado por pares]

American Chemical Society (ACS)

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Título:
Redical and Molecular Yields in the y-Irradiation of Liquid Methanol
Autor: Adams, G. E. ; Baxendale, J. H.
Assuntos: AROMATICS ; CHEMICAL REACTIONS ; FREE RADICALS ; GAMMA RADIATION ; IRON COMPOUNDS ; METHANOL ; MOLECULES ; OXIDATION ; QUINONES ; RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY ; RADIATION EFFECTS ; REDUCTION ; SOLUTIONS ; SULFURIC ACID
É parte de: Journal of the American Chemical Society, 1958-08, Vol.80 (16)
Notas: USDOE
Descrição: Fe(III) salts and benzoquinone are reduced duning the gamma - irradiation of methanol and the extent of reduction is a measure of G(radicals). These solutes also decrease G(H2), G(CH4), and G(glycol) while at the same time increasing G(CH2O). The observations are accounted for by the oxidants reacting with the radicals H, CH2OH, and CH, and the results are analyzed to give G(H), Gm(H2), G(CH2OH), G(CH3), G m(CH2 O), Gm(glycol), and G m(CH/sub Appreciable differences in G(H) and G(CH3) are observed between pure methanol and methanol which is 0.1 N in sulfuric acid.
Editor: American Chemical Society (ACS)
Idioma: Inglês

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