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1,2-BIS[BIS(PYRIDIN-2-YL-METHYL)PHOSPHINO] ETHANE AND ITS PdCl2-BASED COMPLEX: SYNTHESIS AND CRYSTAL STRUCTURE

Baranov, A. Yu ; Sukhikh, T. S. ; Artem′ev, A. V.

Journal of structural chemistry, 2022-04, Vol.63 (4), p.658-662 [Periódico revisado por pares]

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Título:
1,2-BIS[BIS(PYRIDIN-2-YL-METHYL)PHOSPHINO] ETHANE AND ITS PdCl2-BASED COMPLEX: SYNTHESIS AND CRYSTAL STRUCTURE
Autor: Baranov, A. Yu ; Sukhikh, T. S. ; Artem′ev, A. V.
Assuntos: Atomic ; Atomic/Molecular Structure and Spectra ; Chelation ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Ethane ; Inorganic Chemistry ; Molecular ; Optical and Plasma Physics ; Phosphines ; Physical Chemistry ; Solid State Physics
É parte de: Journal of structural chemistry, 2022-04, Vol.63 (4), p.658-662
Descrição: 1,2-Bis[bis(pyridin-2-yl-methyl)phosphino]ethane, R 2 PCH 2 CH 2 PR 2 (R = 2-PyCH 2 ), has been synthesized in 92% yield via the reaction of Cl 2 PCH 2 CH 2 PCl 2 with 2-[(trimethylsilyl)methyl]pyridine. Treatment of this phosphine with Pd(COD)Cl 2 affords chelating complex of [PdLCl 2 ] type, wherein the Pd(II) ion displays a square-planar [Pd@Cl 2 P 2 ] geometry.
Editor: Moscow: Pleiades Publishing
Idioma: Inglês

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