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‘Rocha’ pear firmness predicted by a Vis/NIR segmented model

Cavaco, Ana M. ; Pinto, Pedro ; Antunes, M. Dulce ; Silva, Jorge Marques da ; Guerra, Rui

Postharvest biology and technology, 2009-03, Vol.51 (3), p.311-319 [Periódico revisado por pares]

Kidlington: Elsevier B.V

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  • Título:
    ‘Rocha’ pear firmness predicted by a Vis/NIR segmented model
  • Autor: Cavaco, Ana M. ; Pinto, Pedro ; Antunes, M. Dulce ; Silva, Jorge Marques da ; Guerra, Rui
  • Assuntos: Biological and medical sciences ; calibration ; chlorophyll ; correlation ; Diffuse reflectance ; firmness ; Food industries ; Fruit and vegetable industries ; Fundamental and applied biological sciences. Psychology ; least squares ; model validation ; near-infrared reflectance spectroscopy ; new methods ; Non-invasive ; orchards ; pears ; Postharvest ; prediction ; Pyrus communis L ; reflectance ; ripening ; Shelf-life ; simulation models
  • É parte de: Postharvest biology and technology, 2009-03, Vol.51 (3), p.311-319
  • Notas: http://dx.doi.org/10.1016/j.postharvbio.2008.08.013
  • Descrição: We present a segmented partial least squares (PLS) prediction model for firmness of ‘Rocha’ pear ( Pyrus communis L.) during fruit ripening under shelf-life conditions. Pears were collected from three different orchards. Orchard I provided the pears for model calibration and internal validation (set 1). These were transferred to shelf-life in the dark at 20 ± 2 °C and 70% RH, immediately after harvest. External validation was performed on the pears from the other two orchards (sets 2 and 3), which were stored under different conditions before shelf-life. Fruit was followed in the shelf-life period by visible/near infrared reflectance spectroscopy (Vis/NIRS) in the range 400–950 nm. The correlation between firmness and the reflectance at some wavelength bands was markedly different depending on ripening stage. A segmented partial least squares model was then constructed to predict firmness. This PLS model has two segments: (1) unripe and ripening/ripe pears (high firmness); (2) over-ripe pears (low firmness). The prediction is done in two steps. First, a full range model (full model) is applied. When the full model prediction gives a low firmness value, then the over-ripe model is applied to refine the prediction. The full model is reasonably significant in regression terms, robust, but allows only a coarse quantitative prediction (standard deviation ratio, SDR = 2.48, 1.50 and 2.40 for sets 1, 2 and 3, respectively). Also, RMSEP% = 139%, 91% and 56%, indicating large relative errors at low firmness values. The segmented model improved moderately the correlation, and the values of RMSEC, RMSEP and SDR; it improved significantly the RMSEP% (29%, 55% and 31%), providing an improvement of the relative prediction errors at low firmness values. This method improves the ordinary PLS models. Finally, we tested whether chlorophyll alone was enough for a predictive model for firmness, but the results showed that the absorption of chlorophyll alone does not explain the performance of the PLS models.
  • Editor: Kidlington: Elsevier B.V
  • Idioma: Inglês
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  • Realização: ABCD-USP USP   Logos de Redes Sociais: Freepik

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