Idioma:

Effect of the Solvent Nature on Competition of Protonation and Oxidation Processes of FcCOCH3 with Iodine and p-Benzoquinone

Fomin, V. M. ; Shuklina, N. N.

Russian journal of general chemistry, 2023-12, Vol.93 (Suppl 3), p.S774-S781 [Periódico revisado por pares]

Texto completo disponível

Citações Citado por

Título:
Effect of the Solvent Nature on Competition of Protonation and Oxidation Processes of FcCOCH3 with Iodine and p-Benzoquinone
Autor: Fomin, V. M. ; Shuklina, N. N.
Assuntos: Acetonitrile ; Benzoquinone ; Cations ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Ethanol ; Iodine ; Isomerization ; Oxidation ; Oxidizing agents ; Protonation ; Solvents
É parte de: Russian journal of general chemistry, 2023-12, Vol.93 (Suppl 3), p.S774-S781
Descrição: It was shown that by changing the nature of the solvent (dioxane, acetonitrile, ethanol) and oxidant in the system FcCOCH 3 –HClO 4 –Ox (Ox = I 2 , p -benzoquinone) it is possible to regulate the competition of the processes of redox isomerization of ferrocenylcarbenium ion [FcC(OH)CH 3 ] + →[Fc + C(OH)CH 3 ] and oxidation of FcCOCH 3 , and their contribution to the total process of ferrocenium cation formation. The influence of each of the processes on the rate of the other leads to a decrease in the total rate of ferrocenium cation formation.
Editor: Moscow: Pleiades Publishing
Idioma: Inglês

Voltar para lista de resultados