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Exergoenvironmental Analysis of Tetrahydrofuran/Ethanol Separation through Extractive and Pressure-Swing Distillation

Vaz Mangili, Patrick ; Prata, Diego Martinez

Chemical product and process modeling, 2020-12, Vol.15 (4), p.2774 [Periódico revisado por pares]

Berlin: De Gruyter

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  • Título:
    Exergoenvironmental Analysis of Tetrahydrofuran/Ethanol Separation through Extractive and Pressure-Swing Distillation
  • Autor: Vaz Mangili, Patrick ; Prata, Diego Martinez
  • Assuntos: emissions ; ethanol ; exergy analysis ; extractive distillation ; pressure-swing distillation ; tetrahydrofuran
  • É parte de: Chemical product and process modeling, 2020-12, Vol.15 (4), p.2774
  • Descrição: Extractive distillation uses a high-boiling point solvent for changing the relative volatility of the azeotropic mixture, whereas pressure-swing distillation is based on the difference of operating pressures for such a purpose. In this paper, said separation technologies were applied to a tetrahydrofuran/ethanol mixture and compared with regard to their thermodynamic and environmental performances. The former was assessed by determining the total exergy destruction rate and rational efficiency of each configuration, while the latter was evaluated by estimating their respective indirect carbon emissions. The results showed that the pressure-swing process has not only the lowest exergy destruction rate (383.1 kW) but also the lowest CO emission rate (678.7 kg/h), which is mainly due to its lower thermal energy requirements. A sensitivity analysis was then carried out in order to determine how the carbon emissions respond to both the efficiency and the fuel type of the utility boiler.
  • Editor: Berlin: De Gruyter
  • Idioma: Inglês

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