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Phase Transitions in Metal–Organic Frameworks Directly Monitored through In Situ Variable Temperature Liquid-Cell Transmission Electron Microscopy and In Situ X‑ray Diffraction

Lyu, Jiafei ; Gong, Xinyi ; Lee, Seung-Joon ; Gnanasekaran, Karthikeyan ; Zhang, Xuan ; Wasson, Megan C ; Wang, Xingjie ; Bai, Peng ; Guo, Xianghai ; Gianneschi, Nathan C ; Farha, Omar K

Journal of the American Chemical Society, 2020-03, Vol.142 (10), p.4609-4615 [Periódico revisado por pares]

United States: American Chemical Society

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  • Título:
    Phase Transitions in Metal–Organic Frameworks Directly Monitored through In Situ Variable Temperature Liquid-Cell Transmission Electron Microscopy and In Situ X‑ray Diffraction
  • Autor: Lyu, Jiafei ; Gong, Xinyi ; Lee, Seung-Joon ; Gnanasekaran, Karthikeyan ; Zhang, Xuan ; Wasson, Megan C ; Wang, Xingjie ; Bai, Peng ; Guo, Xianghai ; Gianneschi, Nathan C ; Farha, Omar K
  • Assuntos: Chemistry
  • É parte de: Journal of the American Chemical Society, 2020-03, Vol.142 (10), p.4609-4615
  • Notas: ObjectType-Article-1
    SourceType-Scholarly Journals-1
    ObjectType-Feature-2
    content type line 23
    USDOE Office of Science (SC)
    FG02-03ER15457
  • Descrição: Zr6-based metal–organic frameworks (MOFs) with tetratopic organic linkers have been extensively investigated owing to their versatile structural tunability. While diverse topologies and polymorphism in the resulting MOFs are often encountered with tetratopic linkers and Zr6 nodes, reports on phase transitions within these systems are rare. Thus, we have a limited understanding of polymorph transformations, hindering the rational development of pure phase materials. In this study, a phase transition from a microporous MOF, scu-NU-906, to a mesoporous MOF, csq-NU-1008, was discovered and monitored through in situ variable temperature liquid-cell transmission electron microscopy (VT-LCTEM), high-resolution transmission electron microscopy (HRTEM), and in situ variable temperature powder X-ray diffraction (VT-PXRD). It was found that the microporous- to-mesoporous transformation in the presence of formic acid occurs via a concomitant dissolution–reprecipitation process.
  • Editor: United States: American Chemical Society
  • Idioma: Inglês

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