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Highly efficient Tsuji-Trost allylation in water catalyzed by Pd-nanoparticles

Llevot, A ; Monney, B ; Sehlinger, A ; Behrens, S ; Meier, M A R

Chemical communications (Cambridge, England), 2017, Vol.53 (37), p.5175-5178 [Periódico revisado por pares]

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Título:
Highly efficient Tsuji-Trost allylation in water catalyzed by Pd-nanoparticles
Autor: Llevot, A ; Monney, B ; Sehlinger, A ; Behrens, S ; Meier, M A R
Assuntos: Chemical Sciences
É parte de: Chemical communications (Cambridge, England), 2017, Vol.53 (37), p.5175-5178
Notas: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
Descrição: Palladium nanoparticles stabilized by poly(vinylpyrrolidone) catalyze Tsuji-Trost allylations in water with very high turnover numbers. The di-allylation of methylene active compounds and the allylation of bio-based phenols was performed in high yield. The allylation of lignin showed a high selectivity towards the phenolic OH groups.
Editor: England: Royal Society of Chemistry
Idioma: Inglês

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