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Cooperative Nitrile Coordination Using Nickel and a Boron‐Containing Secondary Coordination Sphere

Clapson, Marissa L. ; Sharma, Harvey ; Zurakowski, Joseph A. ; Drover, Marcus W.

Chemistry : a European journal, 2023-03, Vol.29 (17), p.e202203763-n/a [Periódico revisado por pares]

Germany: Wiley Subscription Services, Inc

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  • Título:
    Cooperative Nitrile Coordination Using Nickel and a Boron‐Containing Secondary Coordination Sphere
  • Autor: Clapson, Marissa L. ; Sharma, Harvey ; Zurakowski, Joseph A. ; Drover, Marcus W.
  • Assuntos: Boron ; Chemical reactions ; Chemical synthesis ; Chemistry ; Coordination ; Ethane ; ligand design ; Ligands ; Nickel ; Organonitriles ; phosphorus secondary coordination sphere ; Substrates
  • É parte de: Chemistry : a European journal, 2023-03, Vol.29 (17), p.e202203763-n/a
  • Notas: https://chemrxiv.org/engage/chemrxiv/article‐details/62cdabd327b1e4837836ea9a
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    A previous version of this manuscript has been deposited on a preprint server
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  • Descrição: Metal‐ligand cooperation has emerged as a versatile tool for substrate activation in chemical reactivity. Herein, we provide the synthesis and characterization of a monoboranyl‐containing analogue of the ubiquitous bulky diphosphine ligand, 1,2‐bis(di‐tert‐butylphosphino)ethane, whose reactivity has been examined using nickel. Together, the pairing of nickel and boron provides a platform that allows for the cooperative coordination of organonitriles, giving unusual examples of intermolecularly bound dinickelacycles. Collaborative work: The synthesis of a new monoboranyl ligand scaffold is described. This ambiphilic diphosphine allows for the cooperative coordination of organonitriles in partnership with nickel(0).
  • Editor: Germany: Wiley Subscription Services, Inc
  • Idioma: Inglês
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