Idioma:

Temperature-Dependent Electron Shuffle in Molecular Group13/15 Intermetallic Complexes

Ganesamoorthy, Chelladurai ; Blaser, Dieter ; Wolper, Christoph ; Schulz, Stephan

Angewandte Chemie (International ed.), 2014-10, Vol.53 (43), p.11587-11591 [Periódico revisado por pares]

Texto completo disponível

Citações Citado por

Título:
Temperature-Dependent Electron Shuffle in Molecular Group13/15 Intermetallic Complexes
Autor: Ganesamoorthy, Chelladurai ; Blaser, Dieter ; Wolper, Christoph ; Schulz, Stephan
Assuntos: Bonding strength ; Chemical bonds ; Cleavage ; Formations ; Insertion ; Intermetallics
É parte de: Angewandte Chemie (International ed.), 2014-10, Vol.53 (43), p.11587-11591
Notas: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Descrição: Monovalent RAl (R=HC[C(Me)N(2,6-iPr2C6H3)]2) reacts with E2Et4 (E=Sb, Bi) with insertion into the weak EE bond and subsequent formation of RAl(EEt2)2 (E=Sb 1; Bi 2). The analogous reactions of RGa with E2Et4 yield a temperature-dependent equilibrium between RGa(EEt2)2 (E=Sb 3; Bi 4) and the starting reagents. RIn does not interact with Sb2Et4 under various reaction conditions, but formation of RIn(BiEt2)2 (5) was observed in the reaction with Bi2Et4 at low temperature.
Editor: Weinheim: Wiley Subscription Services, Inc
Idioma: Inglês

Voltar para lista de resultados

Anterior Resultado 13 Avançar Ir para próxima página