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Sensitive spectrophotometric determination of hydrogen peroxide in aqueous samples from advanced oxidation processes: Evaluation of possible interferences

Rubio-Clemente, A. ; Cardona, A. ; Chica, E. ; Peñuela, G.A.

Afinidad, 2017-07, Vol.74 (579) [Periódico revisado por pares]

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Título:
Sensitive spectrophotometric determination of hydrogen peroxide in aqueous samples from advanced oxidation processes: Evaluation of possible interferences
Autor: Rubio-Clemente, A. ; Cardona, A. ; Chica, E. ; Peñuela, G.A.
É parte de: Afinidad, 2017-07, Vol.74 (579)
Descrição: Hydrogen peroxide (H2O2) determination in real watersamples was carried out in a simple and sensitiveway. The resulting optimal operating conditions froma 23 full factorial experimental design were 450 nm, 50mm and 6x10-3 M for the absorption wavelength, thequartz cell path length and the final concentration ofthe ammonium monovanadate solution, respectively;allowing the quantification of H2O2 up to 2.94x10-3mM. The proposed analytical method was validatedand the effect of the background matrix was investigated,obtaining a selective method. Additionally, thedeveloped analytical method was applied for studyingthe evolution of H2O2 in the decontamination of watercontaining 6.73x10-5 mM of anthracene and 1.19x10-5mM of benzo[a]pyrene using the UV/H2O2 system. Itwas found that the optimal H2O2 level enabling about45% of mineralisation and a removal of the targetpolycyclic aromatic hydrocarbons higher than 99%was 2.94x10-1 mM, remaining approximately 1.47x10-1 mM of H2O2 after 90 min of treatment.
Editor: Universitat Ramon Llull
Idioma: Catalão

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