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Bis(μ-di-phenyl-phosphan-yl)bis-[(tri-methyl-phosphane)cobalt(I)](Co-Co)

Beck, Robert ; Klein, Hans-Friedrich

Acta crystallographica. Section E, Structure reports online, 2013-11, Vol.69 (Pt 11), p.m604-m604 [Periódico revisado por pares]

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Título:
Bis(μ-di-phenyl-phosphan-yl)bis-[(tri-methyl-phosphane)cobalt(I)](Co-Co)
Autor: Beck, Robert ; Klein, Hans-Friedrich
Assuntos: Metal-Organic Papers
É parte de: Acta crystallographica. Section E, Structure reports online, 2013-11, Vol.69 (Pt 11), p.m604-m604
Notas: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
Descrição: The title compound, [Co2{P(C6H5)2}2(C3H9P)4], was obtained by the addition of di-phenyl-phosphane to a solution of Co(CH3)(C3H9P)4. The dinuclear complex mol-ecule exhibits inversion symmetry with the inversion centre located between the two Co(I) atoms. The short Co-Co distance of 2.3670 (8) Å lies within the range of metal-metal double bonds. As a result of inversion symmetry, the four-membered Co2P2 core is rigorously planar, and the two bridging P(C6H5)2-ligands and the terminal C3H9P ligands are arranged in a pseudo-tetra-hedral fashion about the Co(I) atom.
Editor: United States: International Union of Crystallography
Idioma: Inglês

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