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Recent trends and perspectives in electrochemical sensors based on MOF-derived materials

Gonçalves, Josué M ; Martins, Paulo R ; Rocha, Diego P ; Matias, Tiago A ; Julião, Murilo S. S ; Munoz, Rodrigo A. A ; Angnes, Lucio

Journal of materials chemistry. C, Materials for optical and electronic devices, 2021-07, Vol.9 (28), p.8718-8745 [Periódico revisado por pares]

Cambridge: Royal Society of Chemistry

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  • Título:
    Recent trends and perspectives in electrochemical sensors based on MOF-derived materials
  • Autor: Gonçalves, Josué M ; Martins, Paulo R ; Rocha, Diego P ; Matias, Tiago A ; Julião, Murilo S. S ; Munoz, Rodrigo A. A ; Angnes, Lucio
  • Assuntos: Chemical sensors ; Electrochemical analysis ; Electrode materials ; Energy conversion ; Energy storage ; Fuel cells ; Low conductivity ; Metal oxides ; Metal sulfides ; Metal-organic frameworks ; Phosphides ; Sensors ; Storage batteries ; Water splitting
  • É parte de: Journal of materials chemistry. C, Materials for optical and electronic devices, 2021-07, Vol.9 (28), p.8718-8745
  • Notas: Tiago Araújo Matias obtained his BSc degree in Chemistry (2008) and Master of Science degree from the State University of Maringá (2011) in Brazil. In 2011, he joined Prof. Koiti Araki's group at the University of São Paulo (USP) Brazil, where he completed his PhD in 2015 and spent three years as Postdoctoral Researcher. Nowadays, is a postdoctoral researcher in the group of prof. Rodrigo A. A. Munoz at Federal University of Uberlândia. His research interests are coordination chemistry, catalysis, and artificial photosynthesis.
    Josué Martins Gonçalves is a postdoctoral researcher in the group headed by Prof. Lucio Angnes at University of Sao Paulo (USP), Brazil, and has been honored with a prestigious research fellowship from FAPESP. He graduated in Chemistry at University Vale do Acaraú (UVA) in 2014 and received his PhD degree from USP in 2019, under the supervision of Prof. Koiti Araki. His current research interests include the applications of nanomaterials for use in sensors, electrocatalysis, and energy conversion and storage devices.
    Murilo Sérgio da Silva Julião received his PhD degree from the Institute of Chemistry of the University of São Paulo, in 2007. Since 2017, he has been Associate Professor at the University Vale of Acaraú (UEVA), Brazil and FUNCAP Scholarship (BPI). His research interests include the development of biosensors from peroxidases of the plants from the Brazilian Semiarid region, and the study of the redox mechanism of the biological action of secondary metabolites with pharmacological activity.
    Lucio Angnes is a full professor at the Institute of Chemistry of University of Sao Paulo. His research interests include the construction of electrodes with new and alternative materials, development of modified electrodes, arrays of microelectrodes, design of different procedures of enzymes immobilization (on electrodes or inside microchannels), and association of the created devices with flowing systems (flow and batch injection analysis). He has published authored 160 research papers, and is a member of the scientific board of Biosensors & Bioelectronics, Electroanalysis, Journal of Pharmaceutical Research, and actuates as Coordinator of Innovation at FAPESP (São Paulo State Research Foundation). He is also a member of the Sao Paulo State Academy of Science.
    Paulo Roberto Martins received his PhD degree from the Institute of Chemistry, University of Sao Paulo in 2012, under the guidance of Professor Koiti Araki. Currently, he is Assistant Professor at the Federal University of Goiás, Brazil. His research interests are focused on development of new materials based on layered double hydroxides for energy storage purposes.
    Diego Pessoa Rocha is a postdoctoral researcher in the group headed by Prof. Lucio Angnes at University of Sao Paulo (USP), Brazil, and has been honored with a prestigious research fellowship from FAPESP. He graduated in Chemistry (2013), Master in Chemistry (2015), and PhD in Chemistry (2020) from Federal University of Uberlândia, Brazil, under the guidance of Rodrigo A. A. Munoz, who graduated in Chemistry (2002) and received his PhD in Chemistry (2006) from the University of Sao Paulo, Brazil, with an internship period at the Oxford University, UK (2005). He completed his postdoctoral research at the Arizona State University (USA) during 2006-2007 and a postdoctoral research at the University of Sao Paulo during 2007-2008. He is currently Associate Professor of Chemistry at the Federal University of Uberlandia, Brazil, Associate Editor of the Journal of the Brazilian Chemical Society and an affiliate member of the Brazilian Academy of Sciences. His current research interests focus on electrochemical (bio)sensors and devices, 3D-printing technology, and novel materials.
  • Descrição: Metal organic frameworks (MOFs) are hybrid materials built with both organic and inorganic components. The potential of these structures was highlighted in the 1990s and since then, over 90 000 articles dealing with MOFs have been published (still growing rapidly), demonstrating a wide variety of applications. However, an improvement in the electrochemical properties of MOFs is still required to enhance the attributes to satisfy the real and strategic applications of MOF-electrode materials in energy conversion and storage (batteries, supercapacitors, and as catalysts for fuel cells and water splitting), especially in the development of electrochemical sensors. In this sense, being the focus of this review, the great potential of MOF-derived structures for the construction of electrochemical sensors is presented, highlighting the recent advances and strategies on MOF-derived materials, such as metals, metal oxide/hydroxide, metal sulfides, metal phosphides, carbons, or their composites and their potential as electrode materials. In fact, MOF-derived materials exhibit exceptional conductivity, electrochemical activity, and stability, which surpass the relative low conductivity and lack chemical/structural robustness of pristine MOFs, inheriting only the essential structural and compositional properties from their MOF precursors. Considering the demand for highly sensitive and selective electrochemical sensors, MOF-derived materials and their composites have demonstrated relevant advances in electrochemical sensing, as summarized in this review article.
  • Editor: Cambridge: Royal Society of Chemistry
  • Idioma: Inglês
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