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Oxone as an Inexpensive, Safe, and Environmentally Benign Oxidant for C−H Bond Oxygenation

Desai, Lopa V ; Malik, Hasnain A ; Sanford, Melanie S

Organic letters, 2006-03, Vol.8 (6), p.1141-1144 [Periódico revisado por pares]

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Título:
Oxone as an Inexpensive, Safe, and Environmentally Benign Oxidant for C−H Bond Oxygenation
Autor: Desai, Lopa V ; Malik, Hasnain A ; Sanford, Melanie S
Assuntos: Combinatorial Chemistry Techniques ; Indicators and Reagents ; Molecular Structure ; Oxidants - chemistry ; Oxidants - economics ; Peroxides - chemistry ; Sulfuric Acids - chemistry ; Sulfuric Acids - economics
É parte de: Organic letters, 2006-03, Vol.8 (6), p.1141-1144
Descrição: This paper describes the application of peroxide-based oxidants in the Pd(OAc)2-catalyzed acetoxylation and etherification of arene and alkane C−H bonds. Oxone in acetic acid and/or methanol proved particularly effective, and these transformations were applied to a wide variety of substrates.
Editor: United States: American Chemical Society
Idioma: Inglês

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