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A comparative structural study of four para-sulphonato-calix-[4]-arene organic di- and triammonium cation complexes

Da Silva, E ; Nouar, F ; Nierlich, M ; Rather, B ; Zaworotko, M.J ; Barbey, C ; Navaza, A ; Coleman, A.W

Crystal engineering, 2003-09, Vol.6 (3), p.123-135 [Peer Reviewed Journal]

Oxford: Elsevier Ltd

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Title:
A comparative structural study of four para-sulphonato-calix-[4]-arene organic di- and triammonium cation complexes
Author: Da Silva, E ; Nouar, F ; Nierlich, M ; Rather, B ; Zaworotko, M.J ; Barbey, C ; Navaza, A ; Coleman, A.W
Subjects: Aliphatic, non-condensed and condensed benzenic, and alicyclic compounds ; Biochemistry, Molecular Biology ; Calixarene ; Condensed matter: structure, mechanical and thermal properties ; Cross-disciplinary physics: materials science; rheology ; Crystal structure ; Exact sciences and technology ; Growth from solutions ; Life Sciences ; Materials science ; Methods of crystal growth; physics of crystal growth ; Organic clay ; Organic compounds ; Organic diammonium cations ; Physics ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids
Is Part Of: Crystal engineering, 2003-09, Vol.6 (3), p.123-135
Description: The solid state structures of the complexes of para-sulphonato-calix-[4]-arene with putrescine, cadaverine, cis-1,2-cyclohexanediamine and spermidine have been determined. Di- or triammonium cations are included in the calix-[4]-arene molecular cavity and are held in place by hydrogen bonds and hydrophobic interactions. In two of the compounds, diammonium cations are present external to the cavity and are clathrated in tubes formed by the para-sulphonato-calix-[4]-arene network. All four structures show the classic bilayer “organic clay” packing arrangement of opposing para-sulphonato-calix-[4]-arene molecules, with either capsules for the linear diammonium cations, or slipped pairs for the bulky cis-cyclohexane diammonium and triammonium cations.
Publisher: Oxford: Elsevier Ltd
Language: English

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A comparative structural study of four para-sulphonato-calix-[4]-arene organic di- and triammonium cation complexes

Da Silva, E ; Nouar, F ; Nierlich, M ; Rather, B ; Zaworotko, M.J ; Barbey, C ; Navaza, A ; Coleman, A.W

Oxford: Elsevier Ltd

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