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Photoinduced Electron Transfer Reactions of Di(4-methoxyphenyl)ethanal in Solution. Sensitizer-dependent Decay Pathways of the Aldehyde Cation Radical

Akaba, Ryoichi ; Kamata, Masaki ; Kuriyama, Yasunao ; Sakuragi, Hirochika ; Tokumaru, Katsumi

Chemistry letters, 1993-07, Vol.22 (7), p.1157-1160 [Periódico revisado por pares]

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Título:
Photoinduced Electron Transfer Reactions of Di(4-methoxyphenyl)ethanal in Solution. Sensitizer-dependent Decay Pathways of the Aldehyde Cation Radical
Autor: Akaba, Ryoichi ; Kamata, Masaki ; Kuriyama, Yasunao ; Sakuragi, Hirochika ; Tokumaru, Katsumi
Assuntos: Chemistry ; Exact sciences and technology ; General and physical chemistry ; Photochemistry ; Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
É parte de: Chemistry letters, 1993-07, Vol.22 (7), p.1157-1160
Descrição: Laser flash photolyses of di(4-methoxyphenyl)ethanal in the presence of electron-accepting sensitizers such as 2,4,6-triphenylpyrylium tetrafluoroborate and 9,10-dicyanoanthracene have been carried out. Chemical properties of the sensitizers or their one-electron reduced species and an added electrolyte greatly influenced the reaction course of the photogenerated aldehyde cation radical in solution.
Editor: Tokyo: The Chemical Society of Japan
Idioma: Inglês

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