skip to main content
Idioma:

The chemical physics of sequential infiltration synthesis—A thermodynamic and kinetic perspective

Waldman, Ruben Z. ; Mandia, David J. ; Yanguas-Gil, Angel ; Martinson, Alex B. F. ; Elam, Jeffrey W. ; Darling, Seth B.

The Journal of chemical physics, 2019-11, Vol.151 (19), p.190901-190901 [Periódico revisado por pares]

Melville: American Institute of Physics

Texto completo disponível

Citações Citado por
  • Título:
    The chemical physics of sequential infiltration synthesis—A thermodynamic and kinetic perspective
  • Autor: Waldman, Ruben Z. ; Mandia, David J. ; Yanguas-Gil, Angel ; Martinson, Alex B. F. ; Elam, Jeffrey W. ; Darling, Seth B.
  • Assuntos: Atomic layer epitaxy ; Chemical reactions ; Chemical synthesis ; Complex formation ; Functional groups ; Infiltration ; Inorganic materials ; Nanotechnology devices ; Organic chemistry ; Physics ; Polymers ; Porous materials ; Precursors ; Reaction kinetics ; Solid surfaces
  • É parte de: The Journal of chemical physics, 2019-11, Vol.151 (19), p.190901-190901
  • Notas: ObjectType-Article-1
    SourceType-Scholarly Journals-1
    ObjectType-Feature-2
    content type line 23
    USDOE
  • Descrição: Sequential infiltration synthesis (SIS) is an emerging materials growth method by which inorganic metal oxides are nucleated and grown within the free volume of polymers in association with chemical functional groups in the polymer. SIS enables the growth of novel polymer-inorganic hybrid materials, porous inorganic materials, and spatially templated nanoscale devices of relevance to a host of technological applications. Although SIS borrows from the precursors and equipment of atomic layer deposition (ALD), the chemistry and physics of SIS differ in important ways. These differences arise from the permeable three-dimensional distribution of functional groups in polymers in SIS, which contrast to the typically impermeable two-dimensional distribution of active sites on solid surfaces in ALD. In SIS, metal-organic vapor-phase precursors dissolve and diffuse into polymers and interact with these functional groups through reversible complex formation and/or irreversible chemical reactions. In this perspective, we describe the thermodynamics and kinetics of SIS and attempt to disentangle the tightly coupled physical and chemical processes that underlie this method. We discuss the various experimental, computational, and theoretical efforts that provide insight into SIS mechanisms and identify approaches that may fill out current gaps in knowledge and expand the utilization of SIS.
  • Editor: Melville: American Institute of Physics
  • Idioma: Inglês
Links
Voltar para lista de resultados
Ir para página anteriorAnterior Resultado  9 AvançarIr para próxima página

  • Realização: ABCD-USP USP   Logos de Redes Sociais: Freepik

Buscando em bases de dados remotas. Favor aguardar.