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Studies on the reaction of nitric oxide with α,β-unsaturated hydrazones

Yang, Desuo ; Luo, Xiaolin ; Zhu, Haiyun ; Guo, Yaning ; Wu, Longmin

Canadian journal of chemistry, 2012-06, Vol.90 (6), p.510-516 [Periódico revisado por pares]

Ottawa: NRC Research Press

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Título:
Studies on the reaction of nitric oxide with α,β-unsaturated hydrazones
Autor: Yang, Desuo ; Luo, Xiaolin ; Zhu, Haiyun ; Guo, Yaning ; Wu, Longmin
Assuntos: addition électrophile ; Carbon ; electrophilic addition ; hydrazone α,β-insaturée ; Hydrazones ; nitration reaction ; Nitric oxide ; Nitrogen dioxide ; oxyde nitrique ; réaction de nitration ; Stereoselectivity ; α,β-unsaturated hydrazone
É parte de: Canadian journal of chemistry, 2012-06, Vol.90 (6), p.510-516
Descrição: α,β-Unsaturated arylhydrazones ( 1 ) reacted with nitric oxide (NO) in the presence of a trace of oxygen to give α- ( 2a – 2c , 2e , and 2f ) or β-nitro ( 2d and 2g ) unsaturated hydrazones in good yield and with high stereoselectivity. The reaction occurs most likely by an electrophilic addition of NO 2 to the carbon–carbon double bond of 1 at its α- or β-position.
Editor: Ottawa: NRC Research Press
Idioma: Inglês

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