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Review: Oxygen-deficient tungsten oxides
Bandi, Suresh ; Srivastav, Ajeet K.
Journal of materials science, 2021-04, Vol.56 (11), p.6615-6644
[Periódico revisado por pares]
New York: Springer US
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Título:
Review: Oxygen-deficient tungsten oxides
Autor:
Bandi, Suresh
;
Srivastav, Ajeet K.
Assuntos:
Characterization and Evaluation of Materials
;
Chemical synthesis
;
Chemistry and Materials Science
;
Classical Mechanics
;
Crystallography
;
Crystallography and Scattering Methods
;
Hypoxia
;
Materials Science
;
Metal oxides
;
Oxides
;
Oxygen
;
Polymer Sciences
;
Review
;
Solid Mechanics
;
Stoichiometry
;
Tungsten
;
Tungsten compounds
;
Tungsten oxides
É parte de:
Journal of materials science, 2021-04, Vol.56 (11), p.6615-6644
Descrição:
Oxygen-deficient/non-stoichiometric tungsten oxides are a distinct class between two only stoichiometric tungsten oxides, i.e., WO 3 and WO 2 . The WO 3 could be termed as a parent structure while understanding the non-stoichiometric tungsten oxides. The oxygen vacancies ( O vacs ) induced in the parent (WO 3 ) structures cause the re-adjustment of atomic arrangement to compensate for the oxygen deficiency and follow the crystal chemistry. The degree of O vacs determines the range of WO 3-x . The W 18 O 49 (WO 2.722 ) is the highest oxygen-deficient stable phase. These non-stoichiometric oxides proved superior to WO 3 for various applications. Thus, the composition, chemistry, crystallography, synthesis, and formation mechanisms of such materials have been elaborated. Further, the superiority of the materials in view of few applications is well discussed. Finally, the importance of non-stoichiometry/ O vacs in metal oxides for various functional applications can be understood. Graphical abstract
Editor:
New York: Springer US
Idioma:
Inglês
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