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Neutral Radical Molecular Conductors Based on a Gold Dimethoxybenzenedithiolene Complex with and without Crystal Solvent

Yokomori, So ; Dekura, Shun ; Ueda, Akira ; Higashino, Toshiki ; Mori, Hatsumi

Chemistry letters, 2023-01, Vol.52 (1), p.25-28 [Periódico revisado por pares]

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Título:
Neutral Radical Molecular Conductors Based on a Gold Dimethoxybenzenedithiolene Complex with and without Crystal Solvent
Autor: Yokomori, So ; Dekura, Shun ; Ueda, Akira ; Higashino, Toshiki ; Mori, Hatsumi
Assuntos: Bonding strength ; Conductors ; Dimerization ; Gold ; Hydrogen bonds ; Magnetic properties ; Radicals ; Solvents
É parte de: Chemistry letters, 2023-01, Vol.52 (1), p.25-28
Descrição: Two new neutral radical molecular conductors consisting of a gold dimethoxybenzenedithiolene complex have been successfully synthesized. In these crystals, the π–π stacking manners were significantly altered by the formation of weak hydrogen bonds upon the inclusion of a crystal solvent. Reflecting the structural changes, transport and magnetic properties above transition temperatures were modulated by reduced spin dimerization.
Editor: Tokyo: The Chemical Society of Japan
Idioma: Inglês;Francês;Alemão;Japonês

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