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Preparation of Polycarbonate/Clay Nanocomposite and Characterization by X-Ray, Thermal Analyzes and Low-Field Nuclear Magnetic Resonance

Merat, P P ; Tavares, MIB ; da Silva, EO

Journal of materials science and engineering. A, 2011-10, Vol.1 (5), p.671-677

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  • Título:
    Preparation of Polycarbonate/Clay Nanocomposite and Characterization by X-Ray, Thermal Analyzes and Low-Field Nuclear Magnetic Resonance
  • Autor: Merat, P P ; Tavares, MIB ; da Silva, EO
  • Assuntos: Molecular structure ; Montmorillonite ; Nanocomposites ; Nanomaterials ; Nanostructure ; Nuclear magnetic resonance ; Polycarbonates ; X-rays ; X射线衍射分析 ; 低场核磁共振 ; 制备 ; 差示扫描量热法 ; 热分析 ; 玻璃化转变温度 ; 纳米复合材料 ; 聚碳酸酯
  • É parte de: Journal of materials science and engineering. A, 2011-10, Vol.1 (5), p.671-677
  • Notas: Low-field NMR, polycarbonate, nanocomposite
    The nanocomposites based on polycarbonate and organophilic montmorillonite were prepared by solvent cast method, using different ratios of organophilic montmorillonite. The intermolecular interactions and molecular dynamics of the nanocomposites obtained have been evaluated by spin-lattice relaxation time determined by nuclear magnetic resonance. They have also been characterized by X-ray diffraction to confirm the changes in the organoclay structure after being incorporated in the polymeric matrix. The thermal stability of both polymer and nanocomposites were also studied by thermogravimetric analysis. The glass transition temperature was determined by differential scanning calorimetry. The sum of all results indicates that nanocomposites obtained presented a predominant intercalated morphology.
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  • Descrição: The nanocomposites based on polycarbonate and organophilic montmorillonite were prepared by solvent cast method, using different ratios of organophilic montmorillonite. The intermolecular interactions and molecular dynamics of the nanocomposites obtained have been evaluated by spin-lattice relaxation time determined by nuclear magnetic resonance. They have also been characterized by X-ray diffraction to confirm the changes in the organoclay structure after being incorporated in the polymeric matrix. The thermal stability of both polymer and nanocomposites were also studied by thermogravimetric analysis. The glass transition temperature was determined by differential scanning calorimetry. The sum of all results indicates that nanocomposites obtained presented a predominant intercalated morphology.
  • Idioma: Chinês;Inglês

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