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Synthesis of 2,3-diiodoindenes and their applications in construction of 13H-indeno[1,2-l]phenanthrenes

Zhou, Chao ; Chen, Xiaopeng ; Lu, Ping ; Wang, Yanguang

Tetrahedron, 2012-04, Vol.68 (13), p.2844-2850 [Peer Reviewed Journal]

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Title:
Synthesis of 2,3-diiodoindenes and their applications in construction of 13H-indeno[1,2-l]phenanthrenes
Author: Zhou, Chao ; Chen, Xiaopeng ; Lu, Ping ; Wang, Yanguang
Subjects: 2,3-Diiodoindenes ; Alicyclic compounds ; Alicyclic compounds, terpenoids, prostaglandins, steroids ; Chemical reactions ; Chemistry ; Computer programs ; Construction ; Exact sciences and technology ; Fluorescent materials ; Gaussian ; Indene ; Indenophenanthrene ; Iodine-mediated electrophilic cyclization ; Mathematical analysis ; Nuclear magnetic resonance ; Organic chemistry ; Preparations and properties ; Scholl oxidative coupling ; Spectra
Is Part Of: Tetrahedron, 2012-04, Vol.68 (13), p.2844-2850
Notes: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Description: A series of 2,3-diiodoindene were synthesized at first, and 13H-indeno[1,2-l]phenanthrenes were then constructed via a Suzuki coupling reaction and subsequently a Scholl reaction. Structures of synthesized compounds were fully characterized by 1H NMR, 13C NMR, and HRMS. Their photophysical properties, such as UV–vis and FL spectra were investigated, and electronic properties were theoretically calculated by the software of Gaussian 03. The results suggested that these modified indene and indenophenanthrene compounds might have potential applications as light emitting materials. [Display omitted]
Publisher: Kidlington: Elsevier Ltd
Language: English

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